【摘要】 测定了6个系列18种四氮杂芳氧基取代酞菁金属配合物(R4PcM,R=4-吡啶氧基、8-喹啉氧基、2-甲基-8-喹啉氧基;取代位置分别为:α位及β位;M=Ni(Ⅱ),Cu(Ⅱ),Zn(Ⅱ))的UV-Vis吸收光谱。探讨了中心金属、取代基种类及取代位置、溶剂对酞菁金属配合物UV-Vis吸收光谱中Q带最大吸收波长(λmax)的影响,实验结果表明:标题配合物的Q带λmax在680 nm左右;与相同中心金属无取代酞菁金属配合物(669~671 nm)比较,标题配合物的Q带λmax都发生了不同程度的红移;当取代基在α位时其种类对标题配合物Q带λmax的影响较在β位时显著,且相同取代基及中心金属的α位取代配合物的Q带λmax较β位取代配合物的红移更为明显;中心金属、溶剂对标题配合物的Q带λmax影响不明显。更多还原

【Abstract】 UV-Vis absorption spectras of six series（18 kinds） of tetra-azo-aromaticoxy substituted metallophthalocyanines（R₄PcM,R=4-pyridyloxy,8quinolinoxy,2-methyl-8-quinolinoxy;substitution position: α position and β position;M=Ni（Ⅱ）,Cu（Ⅱ）,Zn（Ⅱ）） were measured.The effects of central mentals,the kinds and the positions of substitution groups,and solvents on the metallophthalocyanines’ λ_max in Q-band were discussed.Experimental data show: The λ_max in Q-band of title complexes is about 680 nm.In contrast with substitution-free metallophthalocyanines（669-671 nm）,the λ_max in Q-band of the title complexes with the same central metal exhibits a different red-shift.The effect of substitution group’s kinds on λ_max in Q-band of the title complexes is more obvious in α position than in β position,and with the same substitution group and central metal,λ_max in Q-band of α position substituted complexes exhibits more obvious red-shift than β position substituted complexes.The effects of central metal and solvent on λ_max in Q-band of the title complexes aren’t obvious.更多还原