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噪声对近红外光谱分析的影响及相应的数学处理方法
The Effects of Noise on NIR Analysis and Related Mathematic Pretreatments and Models
【摘要】 以玉米籽粒的粉末样品为例,对噪声较高近红外光谱分析仪进行近红外分析的可行性进行了分析。结果表明,采用四次平均光谱,不采取其他数据处理,使用PLS算法,自编软件CAU-NIR可以得到很好的预测模型。通过与其他噪声较低近红外分析仪预测结果的对比,噪声较高的光栅型近红外光谱分析仪预测样品的相关系数高达98%,变异系数为6·2%。因此当近红外光谱分析仪器的信噪比低于105时,借助一定的软件技术,仍然可以用于定量分析。
【Abstract】 The feasibility of using a relatively high noise NIR spectrometer for analysis was examined by using maize powder samples. The results showed that with four-time averaged NIR spectrum data without more pretreatments, PLS mathematic models and CAU-NIR software, the relative high noise scan NIR spectrometer could be used to get satisfied prediction results compared with other low noise NIR spectrometers. The prediction coefficient could reach 98% and the CV(variation coefficient) was 6.2%. It was proved that when the S/N of NIR spectrometer was lower than 10~5, it still could be used for quantity analysis with the help of some mathematic pretreatments and models.
【Key words】 Near infrared spectroscopy; Noise; Mathematic pretreatment; Mathematic models;
- 【文献出处】 光谱学与光谱分析 ,Spectroscopy and Spectral Analysis , 编辑部邮箱 ,2006年05期
- 【分类号】O433.4
- 【被引频次】48
- 【下载频次】565