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高温纯铁熔体中外加氮化钛超细颗粒的研究

Study on Super-fine Particle of TiN Added into Molten Pure Iron

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【作者】 王国承方克明王铁明

【Author】 Wang Guocheng~1,Fang Keming~1,Wang Tieming~2(1.Metallurgy and Ecological Engineering School,University of Science and Technology Beijing,Beijing 100083,China;2.Technical Center,Chengde Iron & Steel Company,Chengde 067002,Hebei,China)

【机构】 北京科技大学冶金与生态工程学院承德钢铁公司技术中心 北京100083北京100083河北承德067002

【摘要】 在高温纯铁熔体中加入平均尺寸为2.7μm的TiN颗粒,熔炼后得到铸锭试样。用扫描电镜(SEM)及能谱(EDS)研究了铸锭金相试样及电解分离出来的非金属夹杂物的形貌、大小及组成。结果显示夹杂物中存在较多的含Ti夹杂,在部分含Ti夹杂物的表面发现有MnS夹杂物,呈白色点状分布或包覆于颗粒表面;另有部分TiN颗粒与熔体中的夹杂物发生了机械复合,形成相界面清晰的复合夹杂物。并从理论上分析了TiN颗粒在纯铁熔体中的热力学稳定性。

【Abstract】 The ingot specimen was obtained by melting industrial pure iron in which TiN particle with 2.7 μm size was added.The existent state and chemical component of nonmetallic inclusions in the metal-phase sample were investigated with SEM and EDS.The characteristic of nonmetallic inclusions extracted from ingot by the electrolytic method in the nonaqueous solution,such as morphology,size and chemical component,were studied with SEM and EDS.Experimental results show that there were high Ti contain in inclusions.There were a lot of white punctate MnS inclusions at some surface of Ti inclusions.Some TiN particle combined automatically with the inclusion in the molten.At last,the thermodynamic stability of TiN particle in molten pure iron was analyzed.

【关键词】 纯铁氮化钛超细颗粒热力学夹杂物
【Key words】 pure ironTiNsuper-fine particlethermodynamicinclusion
  • 【文献出处】 钢铁钒钛 ,Iron Steel Vanadium Titanium , 编辑部邮箱 ,2006年02期
  • 【分类号】TG115
  • 【被引频次】21
  • 【下载频次】253
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