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用铅锌尾矿和页岩制备高C3S硅酸盐水泥熟料的研究

Study on Production of High Tricalcium Silicate Portland Cement Clinker by Lead-Zinc Tailing and Shale

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【作者】 朱建平宫晨琛兰祥辉李东旭

【Author】 ZHU Jian-ping, GONG Chen-chen,LAN Xiang-hui, LI Dong-xu(College of Materials Science and Engineer, Nanjing University of Technology, Nanjing 210009)

【机构】 南京工业大学材料科学与工程学院南京工业大学材料科学与工程学院 南京210009南京210009

【摘要】 研究了采用铅锌尾矿和页岩配制的高C3S硅酸盐水泥生料的易烧性及所得熟料的性能。设计了18个熟料组成并分别在1350℃,1400℃,1450℃和1500℃下进行煅烧,对所得熟料作游离氧化钙及X射线衍射测试。结果表明1500℃下可以制备出C3S含量达74.52%的熟料。在工业回转窑正常煅烧温度下烧成了C3S含量达70.71%的熟料。部分熟料中加入4%的石膏制得水泥,其性能符合强度等级52.5R的硅酸盐水泥标准要求。加入20%尾矿粉后水泥可满足普通水泥42.5R的强度要求,掺加30%尾矿粉后水泥可达到普通水泥32.5R的强度要求。

【Abstract】 The burnability of the high tricalcium silicate Portland cement raw meal produced by lead-zinc tailing and shale and property of the resulting clinker were studied in this work. 18 clinker compositions were designed and burned at 1350℃, 1400℃, 1450℃ and 1500℃. The resultant clinker was analyzed of the content of free lime,and X-ray diffraction analysis was done. The results show that at 1500℃ a clinker was obtained in which the content of tricalcium silicate is 74.52%. In industrial rotary kiln, a clinker was produced in which the content of tricalcium silicate is 70.71% under normal calcining temperature. The property of the cement from some of the clinker with an addition of 4% gypsum is similar to a Portland cement of 52.5R grade. The cement can meet the standard of Portland cement of 42.5R and 32.5R grade in strengths when added to 20% and 30% lead-zinc tailing powder respectively.

【关键词】 铅锌尾矿页岩硅酸三钙水泥熟料
【Key words】 lead-zinc tailingshaletricalcium silicatecement clinker
【基金】 国家“973”重点基础研究发展规划资助项目(No.2001CB610703).
  • 【文献出处】 硅酸盐通报 ,Bulletin of the Chinese Ceramic Society , 编辑部邮箱 ,2006年05期
  • 【分类号】TQ172.1
  • 【被引频次】19
  • 【下载频次】364
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