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碳羟基磷灰石对废水中Cd2+的吸附

Adsorption of Cd2+ in wastewater by carbonate hydroxylapatite

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【作者】 唐文清曾光明蓝俊康李小明陈朝猛高帅

【Author】 TANG Wen-qing~(1,2),ZENG Guang-ming~(1),LAN Jun-kang~(3),LI Xiao-ming~(1),CHEN Zhao-meng~1,GAO shuai~(2)(1.College of Environmental Science and Engineering,Hunan University,Changsha 410082,China;2.Department of Resources,Environment and Tourism Management,Hengyang Normal University,Hengyang 421008,China;3.Department of Resources and Environmental Engineering,Guilin Universityof Technology,Guilin 541004,China)

【机构】 湖南大学环境科学与工程学院桂林工学院资源与环境工程系衡阳师范学院资源环境与旅游管理系 长沙410082衡阳师范学院资源环境与旅游管理系湖南衡阳421008长沙410082广西桂林541004

【摘要】 利用废弃蛋壳制备碳羟基磷灰石,并利用其吸附废水中的Cd2+.考察了Cd2+初始浓度、pH值、吸附时间、吸附剂用量以及温度等因素对吸附效果的影响,结果表明:当废水中Cd2+初始浓度为30 mg/L、pH=7、吸附时间35 m in、温度35℃时,碳羟基磷灰石对Cd2+去除率高达99.9%.吸附实验还表明该吸附符合Freundlich方程.

【Abstract】 Carbonate hydroxylapatite is first made from abandoned eggshell and used to remove Cd2+from simulated wastewater.The adsorption experiments show that the adsorption effect is controlled by the initial concentration of Cd2+,pH values in wastewater,adsorption period,the consumption of carbonate hydroxylapatite and the reaction temperature.The results also show that the rate of the removal of Cd2+by carbonate hydroxylapatite is increased to 99.9% when the initial concentration of Cd2+in wastewater is 30 mg/L,pH values is 7,adsorption period is 35 min,and the reaction temperature is 35℃.The test proves the adsorption equation is in accordance with Freundlich.

【关键词】 碳羟基磷灰石(CHAP)吸附Cd2+特性
【Key words】 carbonate hydroxylapatite(CHAP)adsorptionCd2+properties
【基金】 国家自然科学基金资助项目(70171055);国家“863”计划资助项目(2004AA649370);湖南省教育厅一般项目(06C184)
  • 【文献出处】 桂林工学院学报 ,Journal of Guilin University of Technology , 编辑部邮箱 ,2006年03期
  • 【分类号】X703.5
  • 【被引频次】18
  • 【下载频次】403
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