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机械振动对聚丙烯结晶作用的影响

THE EFFECT OF MECHANICAL VIBRATION ON CRYSTALLIZATION OF POLYPROPYLENE

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【作者】 薛锋傅伟文李文波程鎔时

【Author】 XUE Feng~1, FU Weiwen~1, LI Wenbo~1, CHENG Rongshi~ 1,2 ( ~1 College of Materials, South China University of Technology, Guangzhou510640)( ~2College of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093)

【机构】 华南理工大学材料科学与工程学院华南理工大学材料科学与工程学院 广州510640广州510640广州51064南京大学化学化工学院南京210093

【Abstract】 The testing specimens of an injected polypropylene sample were subjected to heat treatment for 30 min at various temperatures around its melting peak,and then the treated samples were characterized by DSC.It was found that there existed an temperature window at which the resulting melting temperature and crystallinity of the treated sample increased obviously.For heat treated specimens under static conditions the temperature window occured only below the peak melting temperature.For heat treated specimens under vibration in a dynamic mechanical analyzer with definite amplitude and frequency,this temperature window covered the whole melting range.Heat treating the PP sample under vibration in a temperature range of 5℃ above its melting peak,the resulting specimen possessed a maximum melting temperature.

【关键词】 聚丙烯振动作用熔点结晶度
【Key words】 PolypropyleneVibrationMelt TemperatureCrystallinity
  • 【文献出处】 高分子学报 ,Acta Polymerica Sinica , 编辑部邮箱 ,2006年04期
  • 【分类号】TQ325.14
  • 【被引频次】5
  • 【下载频次】178
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