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三维银配位聚合物[Ag₃（IN）₂（CF₃COO）]的水热合成与晶体结构

Hydrothermal Synthesis and Crystal Structure of a Novel Three-dimensional Silver Coordination Polymer[Ag₃（IN）₂(CF₃COO)]

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【Author】 TIAN Ge,YUAN Hong-Ming,CHEN Yan,LI Guang-Hua,FENG Shou-Hua~*(State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,College of Chemistry,Jilin University,Changchun 130012,China)

【机构】吉林大学无机合成与制备化学国家重点实验室化学学院；吉林大学无机合成与制备化学国家重点实验室化学学院长春130012；长春130012；

【Abstract】 A three-dimensional silver coordination polymer,[(Ag₃（IN）₂(CF₃COO))]（IN=Isonicotinic acid）,was synthesized under mild hydrothermal conditions and characterized by single crystal X-ray diffraction.The compound crystallizes in the triclinic space group P-1,with unit cell parameters a=0.918 48（5） nm,b=1.013 92（6） nm,c=1.067 05（6） nm,Z=2,R₁=0.036 5,wR₂=0.095 5.The Ag centers are bridged by the IN and CF₃CO₂ ligands to form three-dimensional structure.There are strong Ag-Ag bond interaction in the framework.更多还原