【摘要】 使用漫反射傅里叶变换红外光谱(DRIFTS)原位反应器研究了273～333K下甲醛与α-Al2O3颗粒物表面的非均相反应.结果表明,甲醛在α-Al2O3颗粒物表面生成产物主要为甲酸盐、二氧亚甲基以及少量多聚甲醛和吸附态甲醛,甲酸盐是由中间产物二氧亚甲基进一步氧化生成的.在293K下,甲醛在α-Al2O3颗粒物表面的反应级数为0.81±0.05,以样品池几何面积计算的初始摄取系数γ0GEO为(2.3±0.5)×10-5,以颗粒物BET面积计算的初始摄取系数γ0BET为(9.4±1.7)×10-9,表观活化能为33.5kJ/mol.更多还原

【Abstract】 Formaldehyde is one of the most important carbonyl organic compounds.Heterogeneous reactions of formaldehyde on the surface of oxides of crustal elements could be an import sink for formaldehyde in atmosphere.In this study,the kinetics of the heterogeneous reaction of formaldehyde on the surface of α-Al₂O₃ were in situ investigated by diffuse reflectance infrared Fourier transform spectroscopy（DRIFTS）over the temperature range of 273—333 K.The adsorbed species,formate（Ⅰ）,dioxymehtylene（Ⅱ）,polyoxymethylene（Ⅲ）and formaldyhyde（Ⅳ）,on α-Al₂O₃ particles were identified with infrared spectrum:on the surface of α-Al₂O₃ particles,formaldyhyde was oxidized at first to dioxymehtylene which was further oxidized to formate.The reaction order was determined as 0.81±0.05,and the initial reactive uptake coefficients at 293 K were calculated with the geometric and the BET specific surface areas are（2.3±0.5）×10-5 and（9.4±1.7）×10-9,respectively.The apparent activation energy of the reaction was determined as 33.5 kJ/mol.更多还原