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羧基功能化离子液体表面修饰TiO2纳米微粒的制备及结构表征

Preparation and Structural Characterization of Carboxyl-functional Ionic Liquidsurface-modified TiO2 Nanoparticles

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【作者】 张晟卯李健吴志申张平余张治军

【Author】 ZHANG Sheng-Mao+, LI Jian, WU Zhi-Shen, ZHANG Ping-Yu, ZHANG Zhi-Jun (Key Lab for Special Functional Material, Henan University, Kaifeng 475001, China)

【机构】 河南大学特种功能材料重点实验室河南大学特种功能材料重点实验室 开封475001开封475001

【Abstract】 1-Methyl-3-carboxymethyl imidazolium chlorine(\C2OOHmim\Cl) ionic liquid surface-capped TiO 2 nanoparticles were prepared by using tetra-n-butyl titanate ethanol solution as a precursor. The structure of nanoparticles was characterized by FTIR, TEM, XRD and XPS. The results confirmed that \KG-1/5C2OOHmim\·Cl ionic liquid combined with TiO 2 nanoparticles by chelation, the average diameter of TiO 2 nanoparticles was about 8 nm and anatase state was obtained. And only anatase existed even after calcinated at 750 ℃. As to the formation mechanism, we think that the inorganic-organic copolymerized surface-capped layer and repulsive force of positive charge played an important role in the formation and stabilization of TiO 2 nanoparticles.

【基金】 国家自然科学基金(批准号:20401006);河南省自然科学基金(批准号:2004430003,200510475019)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2006年09期
  • 【分类号】O614.411
  • 【被引频次】13
  • 【下载频次】494
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