节点文献
羧基功能化离子液体表面修饰TiO2纳米微粒的制备及结构表征
Preparation and Structural Characterization of Carboxyl-functional Ionic Liquidsurface-modified TiO2 Nanoparticles
【Abstract】 1-Methyl-3-carboxymethyl imidazolium chlorine(\C2OOHmim\Cl) ionic liquid surface-capped TiO 2 nanoparticles were prepared by using tetra-n-butyl titanate ethanol solution as a precursor. The structure of nanoparticles was characterized by FTIR, TEM, XRD and XPS. The results confirmed that \KG-1/5C2OOHmim\·Cl ionic liquid combined with TiO 2 nanoparticles by chelation, the average diameter of TiO 2 nanoparticles was about 8 nm and anatase state was obtained. And only anatase existed even after calcinated at 750 ℃. As to the formation mechanism, we think that the inorganic-organic copolymerized surface-capped layer and repulsive force of positive charge played an important role in the formation and stabilization of TiO 2 nanoparticles.
【Key words】 Carboxyl-functionalized ionic liquid; TiO2 nanoparticles; Chelation; Surface-modification;
- 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2006年09期
- 【分类号】O614.411
- 【被引频次】13
- 【下载频次】494