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改性CF与EVA复合材料的PTC行为研究

Study on PTC Behavior of Modified CF-EVA Composite Materials

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【作者】 王可张国李茁实刘秀奇

【Author】 WANG Ke~(1,2),ZHANG Guo~(1,2*),LI Zhuo-Shi~(1,2),LIU Xiu-Qi~(1,2)(1.College of Materials Science and Engineering,2.Key Laboratory of Automobile Materials of Ministry of Education,Jilin University,Changchun 130012,China)

【机构】 吉林大学材料科学与工程学院吉林大学材料科学与工程学院 吉林大学汽车材料教育部重点实验室长春130012吉林大学汽车材料教育部重点实验室

【Abstract】 Carbon fiber oxidized by KMnO4 was combined with ethylene vinyl acetate(EVA) copolymer,the obtained composite shows a fine stability of thermal cycles and nearly unchanged switching temperature under thermal(cycles),at the same time negative temperature coefficient(NTC) phenomenon is eliminated.Solvent-extraction method is used to examine the interaction between EVA and CF and insolublity with the gel structure were found.The crosslinking network in the gel adsorb CF intensely which makes CF disperse in EVA uniformly,orientate consistently,combine with EVA tightly and shows the elimination of NTC phenomenon.The(switching) temperature of the composite in the heating process is not identical with that of the composite in the cooling process absolutely,but the temperatures in the above two processes are consistent with the outset of melting temperature and the end of crystallization temperature respectively.

【基金】 国家“八六三”计划高性能碳纤维研究与开发重大专项基金(批准号:2002AA304010)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2006年08期
  • 【分类号】TB332
  • 【被引频次】6
  • 【下载频次】148
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