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基于氢键作用由低分子量凝胶因子形成的超分子水凝胶

Supramolecular Hydrogel Formed from Gelator with Low Molecular Weight Based on Hydrogen Bonds

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【作者】 王毓江唐黎明王琰

【Author】 WANG Yu-Jiang,TANG Li-Ming~*,WANG Yan(Advanced Materials Laboratory,Department of Chemical Engineering,Tsinghua University,Beijing 100084,China)

【机构】 清华大学化工系先进材料教育部重点实验室清华大学化工系先进材料教育部重点实验室 北京100084北京100084

【Abstract】 A building unit(defined as SBU) synthesized from 1,2,4,5-benzene tetracarboxylic acid and 4-hydroxy pyridine was used as the gelator with low molecular weight to form supramolecular hydrogels at various concentrations.The dried hydrogels(xerogels) were observed by scanning electron microscope(SEM).The results indicate that the xerogels possess network structures composing of intertwined fibers and the dimension of the fibers can be regulated by the concentration of SBU.Powder X-ray diffraction(XRD) analysis indicates that the fibers are connected by SBU building units.The reversible sol-gel transition of the supramolecular system with the change of temperature was also noticed.

【关键词】 超分子水凝胶凝胶因子形貌
【Key words】 Supramolecular hydrogelGelatorMorphology
【基金】 国家自然科学基金(批准号:20574041)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2006年08期
  • 【分类号】O648.1
  • 【被引频次】15
  • 【下载频次】1049
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