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具有双螺旋链的新型二维无机-有机骨架晶体材料Ni(PDC)(H2O)2的合成与结构

Synthesis,Structure of a Novel Two-dimensional Inorganic-organic Framework Ni(PDC)(H2O)2 with Double Helical Chains

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【作者】 田歌朱广山方千荣辛明红郭晓丹薛铭裘式纶

【Author】 TIAN Ge,ZHU Guang-Shan,FANG Qian-Rong,XIN Ming-Hong,GUO Xiao-Dan,XUE Ming,QIU Shi-Lun~*(State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,College of Chemistry,Jilin University,Changchun 130012,China)

【机构】 吉林大学化学学院无机合成与制备化学国家重点实验室吉林大学化学学院无机合成与制备化学国家重点实验室 长春130012长春130012

【Abstract】 A novel coordination polymer [Ni(PDC)(H2O)2] was synthesized under solvothermal conditions and characterized by means of singlecrystal X-ray diffraction(XRD) analysis,elemental analysis,IR analysis,TG(analysis.) Crystal data for(C7H7NO6Ni) were obtained,(i.e.,) monoclinic(P21/c(No.14),)(a=)(0.720 2(3)) nm,b=0.917 2(4) nm,c=0.128 79(4) nm,β=90.46(3)°,Z=4.The compound was a 2D layered coordination polymer with helical chains.In the compound,there are two helical Ni-O-C and Ni-pdc chains in one layer,and the opposite orientation of the helical chains in the adjacent layers.The layers are connected via hydrogen bonds into 3D supramolecular framework.

【基金】 国家重大基础研究计划项目(批准号:G2000077507);国家自然科学基金(批准号:29873017,20101004)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2006年06期
  • 【分类号】O614.81
  • 【被引频次】14
  • 【下载频次】298
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