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含Sr纳米晶粒二氧化钛多孔微球的制备与表征

Preparation and Characterization of Sr-doped TiO2 Nanocrystal Microspheres

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【作者】 吕幼军石可瑜郭先芝陈鸿健张成何尚锦杜宗杰张保龙

【Author】 L You-Jun,SHI Ke-Yu,GUO Xian-Zhi,CHEN Hong-Jian,ZHANG Cheng,HE Shang-Jin,DU Zong-Jie,ZHANG Bao-Long~*(College of Chemistry,Nankai University,Tianjin 300071,China)

【机构】 南开大学化学学院南开大学化学学院 天津300071天津300071

【Abstract】 Sr-doped nanostructured crystalline TiO2 microspheres were fabricated by modifying the bare microspheres with the method of soaking in strontium nitrate solution and heat treatment.The morphology,crystal structure and photoabsorption ability were characterized by scanning electron microscopy(SEM),X-ray diffraction(XRD) and UV-Vis spectrophotometer.The observation of SEM showed that both the bare and Sr-doped microspheres presented the same honeycomb porous morphology.The XRD spectra affirmed that the incorporation of Sr was in the form of strontium titanate(SrTiO3) as eutectic structure with anatase TiO2.The photocatalytic efficiency of Sr-doped TiO2 microspheres was assessed by monitoring the photodecomposition of KN-R dye.The results reveal that Sr-doped microspheres provided a higher efficiency than the unmodified,which was consistent with the analysis results of UV-Vis absorption spectra.Obvious phenomenon of red-shift on UV-Vis spectrum was seen in comparison with the bare microspheres.Both the phenomena of red-shift and the photocatalytic activity improvement were attributed to the synergistic action between SrTiO3 and anatase TiO2.

【基金】 天津市科技攻关重点研究项目(批准号:043182511)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2006年02期
  • 【分类号】O614.411
  • 【被引频次】9
  • 【下载频次】348
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