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新型树状化合物1,3,5-三{3-[2,4,8,10-四氧杂-9(3,5-二(2,6-二氧杂-4,4-二羟甲基环己基)苯基]螺[5.5]十一烷基}苯的制备

Synthesis of 1,3,5-Tri{3-[2,4,8,10-tetra-oxa-9(3,5-di(2,6-dioxa-4,4-dihydroxymethy lcyclohexyl) phenyl] spiro[5.5] undecyl} benzene for Novel Dendrimer

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【作者】 魏荣宝陈苏战梁娅刘秀明李洪波

【Author】 WEI Rong-Bao~*,CHEN Su-Zhan,LIANG Ya,LIU Xiu-Ming,LI Hong-Bo(College of Biotechnology & Chemical Engineering,Tianjin University of Technology,Tianjin 300191,China)

【机构】 天津理工大学生物技术与化工学院天津理工大学生物技术与化工学院 天津300191天津300191

【Abstract】 Dendrimers are the subject of intense attention recently because of their anticipated potentialities and the peculiar structural properties.A novel synthetic route for the preparation of functionalized dendrons built on the 1,3,5-benzenetricarboxaldehyde core and endowed with a periphery of pentaerythritol groups has been developed.1,3,5-Tri(2,6-dioxa-4,4-dihydroxymethyl cyclohexyl) benzene(1) was synthesized by the condensation of 1,3,5-benzenetricarboxaldehyde with pentaerythritol in the presence of hot CHCl3 and p-methyl benzene sulfonic acid with 55% yield.By turning 1,3,5-benzenetricarboxaldehyde into its trioxime,it was protected to decrease the cross-linked reaction with compound 1 both including many groups.The reaction of compound 1 with 1,3,5-benzenetricarboxaldehyde trioxime and pentaerythritol afforded 1,3,5-tri{3-[2,4,8,10 -tetra-oxa-9(3,5-di(2,6-dioxa-4,4-dihydroxymethylcyclohexyl) phenyl]spiro\undecyl}benzene(2) by using I2 as the catalyst,and the yield was 25.2%.Product 2 and its intermediates were identified by IR,1H NMR,MS spectra and elemental analysis.

【基金】 国家自然科学基金(批准号:20472064);天津市自然科学基金(批准号:040884311)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2006年01期
  • 【分类号】O625
  • 【被引频次】7
  • 【下载频次】135
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