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新型超分子化合物[H₂N（CH₂）₆NH₂]（H₃O）₄[PMo₇^VIMo₅^VO₄₀(V^IVO)₂]晶体的水热合成与表征

Hydrothemal synthesis and crystal structure of a new supramolecular compound [H₂N（CH₂）₆NH₂]（H₃O）₄[PMo₇^VIMo₅^VO₄₀(V^IVO)₂]

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【Author】 DAI Li-mei~ *,1 , BAI Xiu-li~ 2 (1.Department of Chemistry, Heihe University, Heihe 164300,China; 2.Department of Chemistry, Changchun Normal University, Changchun 130032, China)

【机构】 1.黑河学院化学系；长春师范学院化学系黑龙江黑河164300；吉林长春130032；

【摘要】在水热条件下合成了一种新型超分子化合物,通过元素分析、红外光谱、热重分析和X射线单晶衍射方法确定了其晶体结构.结构分析表明:该晶体属于单斜晶系,C2/m空间群,晶胞参数:a=1.2643(3)nm,b=2.1069(4)nm,c=1.0057(2)nm,α=90°,β=110.16(3)°,γ=90°,V=2.5149(9)nm3,Z=2,R1=0.0618,wR2=0.1794.更多还原

【Abstract】 A new supramolecular compound has been synthesized under hydrothermal conditions and characterized by element analysis, IR, TG analysis and single-crystal X-ray diffraction.It shows that the compound crystallizes in the monoclinic system, space group C_ 2 /m, a = 1.264 3(3) nm, b = 2.106 9(4) nm , c = 1.005 7(2) nm, α = 90°, β = 110.16(3)°, γ = 90°, V = 2.514 9(9) nm~3, Z= 2, R_ 1 = 0.061 8, wR_ 2 = 0.179 4.更多还原