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Ni-Al2O3催化剂焙烧温度对丙烷催化还原NO反应性能的影响

Effect of Calcination Temperature on Propane Selective Reduction Nitric Oxide over Ni-Al2O3 Catalysts

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【作者】 张淑娟章福祥李兰冬陈继新关乃佳

【Author】 ZHANG Shu-juan,ZHANG Fu-xiang,LI Lan-dong,CHEN Ji-xin,GUAN Nai-jia~*(Institute of New Catalytic Materials Science,College of Chemistry,Nankai University,Tianjin 300071,China)

【机构】 南开大学化学学院新催化材料研究所南开大学化学学院新催化材料研究所 天津300071天津300071

【Abstract】 The 4% Ni-Al2O3catalysts prepared by coprecipitation method calcined at different temperature was tested by propane selective catalytic reduction of nitric oxide(NO) in excess oxygen.Catalyst calcined at 550 ℃ showed the highest activity for selective catalytic reduction of NO and the NO conversion was approached to 100 % at 500 ℃.The Ni-Al2O3 catalyst was characterized by XRD,temperature-programmed reduction with H2(H2-TPR) and BET techniques.Based on the characterization results,with the increase of calcinations temperature,NiO gradually changes to the surface aluminate phase containing highly dispersed nickel metal cations in Al2O3 matrix,which was responsible for the high activity of catalyst calcined at 550 ℃.At higher calcination temperature,the decrease of surface areas results in the decrease of the activities of the catalyst for NO selective catalytic reduction by propane.

【关键词】 Ni-Al2O3NO选择催化还原丙烷
【Key words】 Ni-Al2O3NOSelective catalytic reductionPropane
【基金】 国家自然科学基金重点项目(20233030);博士点基金(20020055007)
  • 【文献出处】 分子催化 ,Journal of Molecular Catalysis , 编辑部邮箱 ,2006年05期
  • 【分类号】O643.32
  • 【被引频次】10
  • 【下载频次】154
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