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改性羧甲基纤维素膜的制备及其在氨氮废水处理中的应用
Preparation of CMC-Fe Membrane and Study on Application in Electrodialysis for Treating Wastewater
【摘要】 以F eC l3改性羧甲基纤维素(CM C),使得水溶性CM C膜改性为疏水性阳离子交换膜CM C-F e,该膜能稳定存在于酸碱溶液中.用扫描电镜观察其表面形态,IR分析表明改性羧甲基纤维素中的-COOH吸收峰发生了位移.将其应用于电渗析去除高浓度氨氮废水的处理中,结果表明,该膜对氨氮的选择透过性较好,能有效地去除水中氨氮,去除率可达90%.NH4+的迁移过程符合一级反应动力学.
【Abstract】 An insoluble CMC-Fe membrane was prepared by being linked soluble carboxymethyl-cellulose with FeCl3.The membrane as a cationic exchanging membrane in electrodialysis was applied in treating wastewater with high concentration of inorganic ammonia and azote.The results of experiment showed that it was well-selective to ammonia and azote.The percentage of the removal of ammonia and azote in wastewater is up to 90%.The migration process of NH4+ is following one class reaction kinetics.
【关键词】 改性羧甲基纤维素;
离子交换膜;
电渗析;
氨氮;
【Key words】 carboxymethyl-cellulose; ion-exchange membrane; electrodialysis; ammonia and azote;
【Key words】 carboxymethyl-cellulose; ion-exchange membrane; electrodialysis; ammonia and azote;
【基金】 福建省自然科学基金资助项目(A9910009);福建省教育厅资助项目(JB05314JA02189)
- 【文献出处】 福建师范大学学报(自然科学版) ,Journal of Fujian Normal University(Natural Science Edition) , 编辑部邮箱 ,2006年04期
- 【分类号】X703
- 【被引频次】13
- 【下载频次】543