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天然沸石负载壳聚糖去除废水中Cr(Ⅵ)研究

Treatment of Chromium(VI) in Wastewater by Natural Zeolite-chitosan Compound Adsorbent

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【作者】 李增新段春生王彤孟韵

【Author】 Li Zengxin1,2 Duan Chunsheng1 Wang Tong1 Meng Yun1(1 Derartment of Chemistry,Teachers College of Qingdao University,Qingdao 266071;2 College of Environmental Science and Engineering,Donghua University,Shanghai 200051)

【机构】 青岛大学师范学院化学系青岛大学师范学院化学系 青岛266071东华大学环境科学与工程学院上海200005青岛266071

【摘要】 将80目天然沸石与90%脱乙酰度壳聚糖的O.5%醋酸溶液按1∶1.2质量比混合,使壳聚糖负载在天然沸石上,制成固体复合吸附剂,用于去除水中Cr(Ⅵ)。最佳工艺条件是:壳聚糖与天然沸石质量比为0.04,吸附剂用量为8.0g/L,废水中Cr(VI)质量浓度不大于10mg/L,pH值为4~6,吸附平衡时间为40min,Cr(VI)去除率为80%。与活性炭吸附法相比,天然沸石-壳聚糖复合吸附剂吸附效果相近,吸附平衡时间短,成本仅为其1/6。与单一的天然沸石或壳聚糖相比,该吸附剂对Cr(VI)离子的吸附速度快、吸附能力强,成本低。

【Abstract】 80 mesh natural zeolite was added in chitosan slurry of 90% the degree of deacetylation to prepare adsorbent which mass ratio is 1∶1.2.Its adsorptivity toward Cr(Ⅵ) was studied,and the optimal conditions for the Cr(Ⅵ) adsorption by it were: the mass ratio of chitosan and natural zeolite is 0.04,the dosage of the adsorbent is 8.0 g/L,the mass concentration of Cr(Ⅵ) in wastewater does not exceed 10 mg/L,the pH value is 4 ~ 6,the adsorption equilibrium time is about 40 mins and Cr(Ⅵ) removal efficiency is 80%.Compared with the single granular activated carbon or zeolite or chitosan,the adsorbent has a faster adsorption speed,a better adsorbability and low cost price.

【基金】 青岛市科技发展计划项目(项目批准号:05-1-NS-58)
  • 【文献出处】 非金属矿 ,Non-Metallic Mines , 编辑部邮箱 ,2006年04期
  • 【分类号】X703
  • 【被引频次】28
  • 【下载频次】470
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