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MH-Ni蓄电池自放电规律及其应用

Discipline about self-discharge of Ni-MH battery and its application

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【作者】 刘雪省史鹏飞吕军张兆科

【Author】 LIU Xue-sheng1,2,SHI Peng-fei1, LV Jun2, ZHANG Zhao-ke2 (1. Department of Applied Chemistry, Harbin Institute of Technology, Harbin Heilongjiang 150001, China; 2 .Tianjin Lantian High-Tech Power Sources Joint-Stock Co., Ltd., Tianjin 300381, China)

【机构】 哈尔滨工业大学应用化学系天津蓝天高科电源股份有限公司天津蓝天高科电源股份有限公司 黑龙江哈尔滨150001天津蓝天高科电源股份有限公司天津300381黑龙江哈尔滨150001

【摘要】 探讨了MH-Ni蓄电池的自放电变化规律及其在电池筛选方面的应用。MH-Ni蓄电池的自放电率随搁置时间的增加而增大,但增大幅度逐渐变小。其25℃下的变化规律可拟合为Boltzmann函数;蓄电池的自放电率随环境温度的增大而增大;极板表面积影响电池的自放电,搁置初期,电池自放电随极板表面积增大而降低,搁置后期(10~28d),电池自放电随极板表面积增大而增大。电池开路电压越低,其自放电越大。此外,MH-Ni蓄电池自放电率的一致性对循环寿命也有影响,同等条件下,自放电差异小的电池组,其循环寿命优于随机组合的电池组。

【Abstract】 In this paper, both the discipline about self-discharge of Ni-MH battery and its application in cells’ selection have been investigated. The self-discharge rate of Ni-MH battery increases with the increasing of interval in an open circuit state. The discipline about self-discharge at ambient temperature of 25 ℃ could be fitting as Boltzmann function; the self-discharge rate increases with the increasing of ambient temperature; the smaller the open circuit voltage is, the larger the self-discharge rate is. Furthermore, the consistence of the self-discharge rate has an effect on the cycle life of Ni-MH battery. At the same state, the cycle life of the battery of which the self-discharge diversity is smaller, is better than the one which is packed stochastically.

  • 【文献出处】 电源技术 ,Chinese Journal of Power Sources , 编辑部邮箱 ,2006年03期
  • 【分类号】TM912
  • 【被引频次】17
  • 【下载频次】271
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