节点文献
臭氧氧化结合化学吸收同时脱硫脱硝的研究
Simultaneous Desulfurization and Denitrification by Combined Ozone Oxidation and Chemical Scrubbing
【摘要】 为深入研究和开发臭氧氧化结合化学吸收同时脱除多种污染物技术,阐明了石灰石吸收脱除臭氧氧化产物(SOx和NOx)的吸收反应机理,通过气液固平衡理论对石灰石浆液吸收SOx和NOx特性进行了分析研究。理论分析表明:烟气中CO2对SOx和NOx吸收的影响可以忽略,并给出浆液在吸收容量所能承受的最大气液比。当[CaCO3]=0.05 mol/l时,临界点M=600~700;当[CaCO3]=0.1 mol/l时,临界点M=1200~1300;当[CaCO3]=0.15 mol/l时,临界点M=1900~2000。图4表1参9
【Abstract】 The reaction mechanisms of ozone with many pollutants are being elucidated,and the dynamic processes of ozone,oxidizing NOx and SO2,simulated. According to thermodynamic principles,the partial pressures of SOx and NOx,after the flue gas wet state’s simultaneous desulfurization and denitration reactions respectively with Ca(OH)2 and CaCO3,have both attained equilibrium,are then calculated.Calculation results show that as an absorbent,Ca(OH)2 is superior to CaCO3,and both of them exhibit nearly a 100% removal efficiency.Figs 4,table 1 and refs 9.
【Key words】 environmental engineering; desulfurization and denitrification; absorbing characteristic; ozone;
- 【文献出处】 动力工程 ,Journal of Power Engineering , 编辑部邮箱 ,2006年04期
- 【分类号】X701.3
- 【被引频次】37
- 【下载频次】1040