【摘要】 在室温下,水溶液中以碘化四对(4-三甲氨基苯基)钴卟啉和杂多酸为原料合成两种新型有机/无机配合物———钴卟啉/磷钨酸和钴卟啉/钒取代杂多酸。用红外光谱和紫外可见光谱对两种配合物结构表征,确定配合物中仍然保留着卟啉π电子共轭体系和杂多酸的Keggin型结构单元。更多还原

【Abstract】 Two kinds of novel orgnic/inorganic complex—cobaltporphyrin/polyoxometalate were prepared in water solution under room temperatur. Their structures were characterized by IR and UV-Vis spectra.The results show that the porphyrin’s π electron system and the polyoxometalate’s structural unit of Keggin still exist in these kinds of coordinated compounds.更多还原