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添加Sn组元对Ru-Ti-Ir阳极涂层的改性研究

Investigation on Ru-Ti-Ir Anode Coatings Modified by Adding Sn Element

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【作者】 王科韩严王均涛张晓玲孙玉璞

【Author】 WANG Ke~(1,2),HAN Yan~(l),WANG Jun-tao~(*1),ZHANG Xiao-ling~(2),SUN Yu-pu~(2)(1.State Key Laboratory for Marine Corrosion and Protection,Qingdao Branch of Luoyang Ship Material Research Institute,Qingdao 266071,Shandong,China,2.Department of Material Science and Engineering of Shandong University,Jinan 250061,Shandong,China)

【机构】 海洋腐蚀与防护国家级重点实验室 中船重工七二五所青岛分部海洋腐蚀与防护国家级重点实验室中船重工七二五所青岛分部山东大学材料科学与工程学院山东青岛266071山东大学材料科学与工程学院山东济南250061山东济南250061

【摘要】 应用热分解法制备不同Sn含量的Ru-Ti-Ir-Sn氧化物阳极涂层,SEM、EDX、XRD、析氯电位、电流效率及循环伏安和电化学阻抗谱等实验表明,Ru-Ti-Ir经添加Sn组元后,该阳极涂层表面形貌发生了很大变化,Sn组元的添加不仅有利于该阳极涂层析氯电位的降低,而且能够有效提高其电流效率.

【Abstract】 The anode coatings of Ru-Ti-Ir-Sn oxide with various Sn contents were prepared by thermal decomposition and characterized by the scanning electron microscopy(SEM),energy dispersive X-ray detector(EDX),X-ray diffraction(XRD),and the potential of chlorine evolution,current efficiency,cyclic voltammetry and electrochemical impedance spectroscopy(EIS).The results tests showed that there was a great change in the morphology of the coatings after adding Sn element.The addition of Sn not only reduced the potential of chlorine evolution,but also effectively improved the current efficiency of the anode coatings.

【基金】 十五"国防预研项目(YK010402)资助
  • 【分类号】TG174
  • 【被引频次】24
  • 【下载频次】174
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