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化学镀锡反应历程的研究进展

Research process on electroless tin plating reaction mechanism

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【作者】 赵杰李宁傅石友

【Author】 ZHAO Jie,LI Ning,FU Shi-you Department of Applied Chemistry,Harbin Institute of Technology,Harbin 150001,China

【机构】 哈尔滨工业大学应用化学系哈尔滨工业大学应用化学系 黑龙江哈尔滨150001黑龙江哈尔滨150001

【摘要】 化学镀锡主要包括还原法化学镀锡、歧化反应化学镀锡和浸镀法化学镀锡,总结了3种方法的优缺点及反应机理。还原法化学镀锡和歧化反应化学镀锡的镀液稳定性差;浸镀法化学镀锡的镀液稳定性好,镀层厚度均匀,其沉积过程分为置换反应期、铜锡共沉积与自催化沉积共存期和自催化沉积期。化学镀锡工艺在微电子行业具有很好的应用前景。

【Abstract】 The methods of electroless tin plating include processes based on reduction,disproportionation and repla-cement reactions.The advantages and disadvantages and reaction mechanisms of the above methods were summarized.The plating baths based on reduction and disproportionation reactions have poor stability while the replacement-based bath is stable,and the deposit has uniform thickness.The deposition process with replacement reaction includes repla-cement reaction period,copper-tin codeposition and autoca-(talytic) deposition coexisting period,autocatalytic deposition period.The process of electroless tin plating has wide applications in microelectronic filed.

  • 【文献出处】 电镀与涂饰 ,Electroplating & Finishing , 编辑部邮箱 ,2006年08期
  • 【分类号】TG174.44
  • 【被引频次】25
  • 【下载频次】793
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