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梯形(phen)Zn—O—MoO2晶体的水热合成与表征
Hydrothermal synthesis and characterization of ladder type structure(phen)Zn—O—MoO2
【摘要】 利用水热方法合成梯形(phen)Zn—O—MoO2晶体,并用X射线衍射仪对其结构进行了表征.结果表明,(phen)Zn—O—MoO2属单斜晶系:空间群为P2/m;a=0.881 64(17)nm,b=0.643 96(14)nm,c=1.065 9(6)nm,α=γ=90°,β=100.79(3)°,V=0.594 4(4)nm3,Z=2.Zn原子为三角双锥构型,Mo原子为四面体构型,(phen)Zn—O—MoO2为折叠梯形链状结构.
【Abstract】 A crystal of(phen)Zn—O—MoO2 has been synthesized by the hydrothermal method and the structure was determined by single-crystal X-ray diffraction.The title compound crystallizes in the monoclinic space group P2/m,a=0.881 64(17) nm,b=0.643 96(14) nm,c=1.065 9(6) nm,α=γ=90°,β=100.79(3)°,V=0.594 4(4) nm3,Z=2.The Zn atom is the triangle configuration,the Mo atom is the tetrahedral configuration,this compound for folds the trapezoidal chain shape structure.
【关键词】 水热合成;
梯形结构;
晶体;
表征;
【Key words】 hydrothermal synthesis; ladder-tape structure; crystal; characterization;
【Key words】 hydrothermal synthesis; ladder-tape structure; crystal; characterization;
【基金】 国家自然科学基金资助项目(2027102120333070);吉林师范大学重点基金资助项目(200212)
- 【文献出处】 东北师大学报(自然科学版) ,Journal of Northeast Normal University , 编辑部邮箱 ,2006年01期
- 【分类号】O614.612
- 【被引频次】11
- 【下载频次】91