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离子交换富集-原子吸收光谱法测定单矿物中的锰

Atomic Absorption Spectrometry Determination of Trace Manganese in Mineral by Separation and Pro-concentration with ion exchange process

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【作者】 张锂韩国才

【Author】 ZHANG Li~(1,2),HAN Guo-cai~1 (The Basic Course Department of Lanzhou Polytechnic College,Lanzhou,730050,China2.College of Chemistry and Chemical Engineering,Northwest Normal Universit,lanzhou,730070,CHINA)

【机构】 兰州工业高等专科学校基础学科部兰州工业高等专科学校基础学科部 甘肃兰州730050甘肃兰州730050

【摘要】 采用了离子交换分离富集矿样中的锰,该系统与原子吸收测量技术相结合,实现了富集-原子吸收法联用测定矿样中的锰,,该方法检出限(3σ)为0.018μg/L,线性范围0.01~0.5μg/L,相对标准偏差RSD为3.59%。该法应用于标准样品的测定其结果与标准样值相符,应用于实际矿样的测定,加标回收率在96.7%~104.3%之间,结果满意。

【Abstract】 A rapid and sensitive method for concentration and separation of trace manganese based on ion exchange process has been developed.The detection limit of the method is 0.018μg/L.The recoveries are in the range of 96.7% to 104.3% and The relative standard deviations(RSD)are 3.59%.The method has been successfully applied for the determination of manganese in certified reference material GBW07268 and other sample.

  • 【文献出处】 东北电力大学学报 ,Journal of Northeast Dianli University , 编辑部邮箱 ,2006年01期
  • 【分类号】P575.4
  • 【被引频次】1
  • 【下载频次】70
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