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海藻酸钙水凝胶对电刺激的响应行为

Electroresponsive behavior of calcium alginate hydrogel under electric field

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【作者】 刘根起赵晓鹏靖伟伟邵旭丹

【Author】 LIU Genqi ZHAO Xiaopeng JING Weiwei SHAO Xudan Institute of Electrorheological Technology 141#, Department of Applied Physcics, Northwestern Polytechnical University, Xi’an 710072 Department of Applied Chemistry, Northwestern Polytechnical University, Xi’an 710072

【机构】 西北工业大学电流变技术研究所西北工业大学应用化学系西北工业大学应用化学系 西安 710072 西北工业大学应用化学系 西安 710072西安 710072

【摘要】 以CaCl2为交联剂采用浸渍法制备了海藻酸钙水凝胶,研究了海藻酸钙水凝胶的溶胀吸水率及其电刺激响应行为.结果表明,在NaCl水溶液中,海藻酸钙水凝胶的平衡溶胀比随着NaCl溶液浓度的增大而增大,随着交联剂CaCl2溶液浓度的增大而减小.海藻酸钙水凝胶在NaCl水溶液中在非接触直流电场作用下向负极弯曲,其弯曲速度、弯曲偏转程度和应变随着外加电场强度的增大而增大,随着NaCl溶液离子强度的变化在离子强度I=0.03时出现临界最大值,随着交联剂CaCl2溶液浓度的增大而减小.在周期性电场作用下,海藻酸钙水凝胶的弯曲响应行为具有良好的可逆性.

【Abstract】 Calcium alginate hydrogels were prepared by soaking the membranes of sodium alginate in CaCI2 solutions of different concentration, and their swelling ratio and electroresponsive behavior of the hydrogels in NaCl solution were studied. The results indicate that the water take-up of the hydrogels increase with increasing the concentration of NaCI solution and decreased with increasing the concentration of crosslinker of CaCl2 solution. The hydrogels swollen in NaCI solution bend toward cathode under a non-contact direct current electric field. The bending speed and strain of the hydrogels increase as the applied voltage increases, but decrease as the concentration of CaCl2 increases, and reach their maximum values when the ionic strength of NaCI solution is 0.03. Under a cyclically varying electric field, the hydrogels exhibit good reversible bending behavior.

【基金】 国家自然科学基金重大研究计划90101005;国家杰出青年科学基金50025207;西北工业大学英才培养计划基金03XD0106;西北工业大学研究生创业种子基金Z200587资助项目.
  • 【文献出处】 材料研究学报 ,Chinese Journal of Materials Research , 编辑部邮箱 ,2006年05期
  • 【分类号】O648.1
  • 【被引频次】7
  • 【下载频次】359
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