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西藏南部晚白垩世厚壳蛤不同壳层的地球化学特征及其对古海洋信息的保存性

Geochemistry in Different ShellLayers of Rudist Bivalve from Late Cretaceousin the South of Tibet and Preservation for the Information of Sea Water

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【作者】 黄思静卿海若胡作维吴素娟孙治雷裴昌蓉

【Author】 HUANG Si-jing~1 QING Hai-ruo~1 HU Zuo-wei~1 WU Su-juan~1 SUN Zhi-lei~1 PEI Chang-rong~1(1.State Key Laboratory of Oil/Gas Reservoir Geology and Exploitation,Collegeof Geoscience, Chengdu Universityof Technology,Chengdu 610059;2.Department of Geology,University of Regina,Regina SK Canada S4S 0A2)

【机构】 成都理工大学油气藏地质及开发工程国家重点实验室地球科学学院加拿大里贾纳大学地质学系成都理工大学油气藏地质及开发工程国家重点实验室地球科学学院 成都610059加拿大里贾纳S4S0A2成都610059

【摘要】 测试了西藏南部岗巴剖面上白垩统宗山组上段地层中厚壳蛤不同壳层的Sr、Mn、A l、S i含量,以及碳、氧、锶同位素组成,测试结果表明:1)厚壳蛤的不同壳层(包括柱状层、珍珠层和二者间的过渡层)的碳酸盐矿物均已新生变形为成岩低镁方解石(DLMC),各种原始碳酸盐矿物(沉积低镁方解石或文石)都已不同程度地发生重结晶;2)从壳的外层(柱状层)向内层(珍珠层)方向,碳酸盐矿物重结晶作用有逐渐增强的趋势,柱状层仍具有很好的柱状结构,其平均阴极发光强度明显弱于内部的珍珠层;3)厚壳蛤不同壳层的Sr含量和δ18O值都呈现有规律的变化,从靠外部的柱状层到内部的珍珠层,Sr含量和δ18O值都逐渐降低,同样说明内部的珍珠层丢掉的海水信息相对较多;4)厚壳蛤不同壳层和体腔充填物的1δ8O值都显著低于前人报道的同期海水值,说明在新生变形过程中,厚壳蛤不同壳层和体腔充填物的氧同位素都与大气水或其它成岩流体发生了交换,但柱状层的氧同位素与大气水(或其它成岩流体)的交换相对较少;5)厚壳蛤不同壳层和体腔充填物的锶、碳同位素组成与同期海水值接近,不同壳层之间也没有表现出有规律性的变化,因而在矿物的新生变形过程中,厚壳蛤的锶、碳同位素与成岩流体间的交换相对较少,同时也说明,在氧、碳、锶三种同位素中,氧很容易与成岩流体发生同位素交换,而碳、锶同位素则更多地代表了海水信息。

【Abstract】 The concentrations ofMn,Sr,SiO2, Al2O3,and values ofδ13C,δ18Oand 87Sr/86Srhave been measured for different shell layers of rudist bivalvefrom a Late Cretaceoussection in the south of Tibet.The study results are as follows: 1) The constitutionminerals,inthe pillar,pearl and transitionlayers for the shell of rudist bivalvehave totally transposedto diagenetic low magnesiumcalcite(DLMC) by neomorphism and all the original carbonates are recrystallized to a certain extent. 2) The recrystallization ofinner shell layers(pearl or transitionlayer)is much stronger than that of outer shell layer.The outer shelllayer,with duller catholuminescence,has pillar texture. 3) The concentration of Srand value of δ18Odisplays a regular varietyfrom the outer shelllayer(pillar layer) to inner shell layer(pearl layer).The concentration of Srand value of δ18Ofor outershell layer are lower than those of innershell layer,suggesting that the innershell layerlost more information of sea water during neomorphism. 4) The δ18Ovalues of all the shell layers and the celom filling are much lower than those of original sea water reportedby the published papers,so the exchange withmeteoric water(or other diagenetic fluid) in oxygen isotope shouldhave happened during neomorphism of precursoryminerals in the shell,but relatively less exchange happenedin outer shell layer. 5) The carbon and strontium isotope composition of different shell layers is close to the values of coeval sea water,and no regular variation among different shell layers,indicating less exchange with diagenetic fluid in carbon and strontium isotope.The reason is that diagenetic recrystallization of carbonates is accomplished in a system with a low water/ rock ratio for carbon(also for strontium),buta high ratio for oxygen,and thereforethe isotope compositions ofcarbonand strontium contains more information for originalsea water.

【基金】 国家自然科学基金资助项目(批准号:40272059);国家重点基础研究发展规划项目前期研究专项(批准号:2001CCA01800)研究成果
  • 【文献出处】 沉积学报 ,Acta Sedimentologica Sinica , 编辑部邮箱 ,2006年01期
  • 【分类号】P736.22
  • 【被引频次】14
  • 【下载频次】302
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