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硅烷偶联剂改性的二氧化钛光催化降解气相苯(英文)
Gas-Phase Photocatalytic Oxidation of Benzene over Titanium Dioxide Modified by Silane Coupling Agent
【摘要】 用硅烷偶联剂KH-570对二氧化钛光催化剂进行了改性,制备了一种新型光催化剂.以苯作为模拟气体,在静态反应装置中考察了该催化剂的光催化性能.结果表明,KH-570能显著提高二氧化钛对气相苯的光催化降解性能,其转化率是纯二氧化钛的2·5倍.采用红外光谱和X射线光电子能谱对催化剂进行了表征.
【Abstract】 The photocatalytic activity of TiO2 for the decomposition of gaseous benzene in a batch reactor can be greatly improved by modifying TiO2 with 3-(trimethoxysilyl)propylmethacrylate.The photocatalyst prepared was characterized by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy (XPS). The XPS spectrum shows that the binding energy of Ti 2p for the modified TiO2 shifted to a low value. The modified TiO2 has a photocatalytic activity 2.5 times that of pure TiO2.
【关键词】 二氧化钛;
硅烷偶联剂;
改性;
苯;
气相光催化氧化;
【Key words】 titanium dioxide; silane coupling agent; modification; benzene; gas-phase photocatalytic oxidation;
【Key words】 titanium dioxide; silane coupling agent; modification; benzene; gas-phase photocatalytic oxidation;
- 【文献出处】 催化学报 ,Chinese Journal of Catalysis , 编辑部邮箱 ,2006年12期
- 【分类号】O643.32
- 【被引频次】23
- 【下载频次】651