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氧化锰八面体分子筛纳米棒的合成及其催化甲醛低温氧化性能

Synthesis and Catalytic Performance of Manganese Oxide Octahedral Molecular Sieve Nanorods for Formaldehyde Oxidation at Low Temperature

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【作者】 唐幸福黄秀敏邵建军刘俊龙李永刚徐奕德申文杰

【Author】 TANG Xingfu,HUANG Xiumin,SHAO Jianjun,LIU Junlong,Li Yonggang,XU Yide,SHEN Wenjie~*(State Key Laboratory of Catalysis,Dalian Institute of Chemical Physics,The Chinese Academy of Sciences,Dalian 116023,Liaoning,China)

【机构】 中国科学院大连化学物理研究所催化基础国家重点实验室中国科学院大连化学物理研究所催化基础国家重点实验室 辽宁大连116023辽宁大连116023

【Abstract】 Uniform manganese oxide octahedral molecular sieve(OMS-2) nanorods were synthesized by adding a small quantity of K2S2O8 to the solution containing MnSO4·H2O and KMnO4,and used for complete oxidation of formaldehyde.According to the results of N2 adsorption and X-ray diffraction,the material is a manganese oxide octahedral molecular sieve with the cryptomelane type structure.TEM observation shows that the diameters of the nanorods range from 15 to 25 nm, and the lengths are 300~400 nm.Complete conversion of HCHO to CO2 and H2O can be achieved at 353 K over OMS-2,and the same conversion is obtained at 373 K on the MnOx powder under the same conditions,which demonstrates that the catalytic activity is closely related to the morphology of the catalysts.

  • 【文献出处】 催化学报 ,Chinese Journal of Catalysis , 编辑部邮箱 ,2006年02期
  • 【分类号】O643.32
  • 【被引频次】99
  • 【下载频次】879
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