节点文献
氧化锰八面体分子筛纳米棒的合成及其催化甲醛低温氧化性能
Synthesis and Catalytic Performance of Manganese Oxide Octahedral Molecular Sieve Nanorods for Formaldehyde Oxidation at Low Temperature
【Abstract】 Uniform manganese oxide octahedral molecular sieve(OMS-2) nanorods were synthesized by adding a small quantity of K2S2O8 to the solution containing MnSO4·H2O and KMnO4,and used for complete oxidation of formaldehyde.According to the results of N2 adsorption and X-ray diffraction,the material is a manganese oxide octahedral molecular sieve with the cryptomelane type structure.TEM observation shows that the diameters of the nanorods range from 15 to 25 nm, and the lengths are 300~400 nm.Complete conversion of HCHO to CO2 and H2O can be achieved at 353 K over OMS-2,and the same conversion is obtained at 373 K on the MnOx powder under the same conditions,which demonstrates that the catalytic activity is closely related to the morphology of the catalysts.
【Key words】 manganese oxide; octahedral molecular sieve; formaldehyde; oxidation;
- 【文献出处】 催化学报 ,Chinese Journal of Catalysis , 编辑部邮箱 ,2006年02期
- 【分类号】O643.32
- 【被引频次】99
- 【下载频次】879