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复合钒钼酸干凝胶薄膜湿敏元件的复阻抗谱

Complex impedance plots of poly-vanadium-molybdenum acid xerogel thin film humidity elements

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【作者】 李莉童茂松翁爱华

【Author】 LI Li~1,TONG Mao-song~2,WENG Ai-hua~3(1.School of Chemistry and Chemical Engineering,Daqing Petroleum Institute,Daqing 163318,China;2.Well Logging Company,Daqing Petroleum Administrative Bureau,Daqing 163412,China;3.College of Geoexploration Science and Technology,Jilin University,Changchun 130026,China)

【机构】 大庆石油学院化学化工学院大庆石油管理局测井公司吉林大学地球探测科学与技术学院 黑龙江大庆163318黑龙江大庆163412吉林长春130026

【摘要】 采用溶胶凝胶法制备了复合钒钼酸H2V12-xMoxO31±y.nH2O(0≤x≤4.0)干凝胶薄膜湿敏元件,对其进行了复阻抗谱分析,结果表明:随着x的增加,对应的阻抗谱半圆的半径逐渐变大,x≥2.5时,电极表面接触部分在阻抗谱低频端开始体现,x=2.0时,阻抗值较大,且不受频率影响,元件性能较好;测试频率为1 kHz时,H2V8.5Mo3.5O32.nH2O干凝胶薄膜湿敏元件在全湿度范围内,其阻抗湿度曲线线性良好,灵敏度较高。

【Abstract】 Poly-vanadium-molybdenum acid H2V12-xMoxO31±y·nH2O(0≤x≤4.0) xerogel thin films humidity elements are prepared by sol-gel process,and its complex impedance plots are analyzed.Results show that the radius of semicircle of the complex impedance plots for poly-vanadium-molybdenum acid xerogel thin films increase with increasing of x.When x≥2.5,in the low-frequency range,the contact part of the total impedance for electrode appears.The properties of humidity elements are best as x=2.0,while the complex impedance is higher and no relationship with frequency.H2V8.5Mo3.5O32·nH2O xerogel thin film humidity element has good linear and high sensitivity in total relative humidity range at 1 kHz.

【基金】 国家自然科学基金资助项目(40304009)
  • 【文献出处】 传感器与微系统 ,Transducer and Microsystem Technologies , 编辑部邮箱 ,2006年05期
  • 【分类号】TP212
  • 【被引频次】4
  • 【下载频次】102
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