【摘要】 用热力学方法处理过渡状态理论的艾林方程,选择两种不同参考点作为标准态,得出两个不同的计算公式,两种类型的活化自由能、活化焓、活化熵意义数值不同,对于理想气体的反应,两种类型的活化焓相等,活化熵不等,但两种活化熵之间存在定量关系式:△_r~≠S_m~φ(P~φ)=△_r~≠S_m~φ(c~φ)+(n-1)R1n(P~φ)/RTc~φ。更多还原

【Abstract】 By two distinct standard states,different expressions calculating rate coefficient of reaction can be deduced from Eyring equation in transition state theory with thermodynamic method.In such conditions,the meanings and numbers of Gibbs free energy,entropy and enthalpy of activation are disparate.However for two kinds of enthalpy of activation,numeriacal value is equal.And it can be linked with the relation of △_r~≠S_m~φ(P~φ)=△_r~≠S_m~φ(c~φ)+(n-1)R1n(P~φ)/RTc~φ.更多还原