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表面改性方法对PP/Mg(OH)2无卤阻燃体系性能的影响

INFLUENCE OF SURFACE TREATMENT OF MAGNESIUM HYDROXIDE ON THE PROPERTIES OF PP/Mg(OH)2 NONHALOGENIC FLAME-RETARDANT SYSTEM

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【作者】 张志永冯钠李书娟孙忠祥刘海龙郑长富尹建志

【Author】 Zhang Zhiyong~(1),Feng Na ~(1),Li Shujuan~(1),Sun Zhongxiang~(2),Liu Hailong~(2),Zheng Changfu ~(1),Yin Jianzhi ~(1)(1.Department of Chemical and Material Engineering,Dalian Institute of Light Industry,Dalian 116034,China;2.Dalian Yatai Science and Technology New Material Company,Dalian 116001,China)

【机构】 大连轻工业学院化工材料学院大连亚泰科技新材料有限公司大连轻工业学院化工材料学院 大连116034大连116034大连116001

【摘要】 以聚丙烯(PP)为基体树脂,加入采用不同表面改性方法处理的氢氧化镁[Mg(OH)2]制备无卤阻燃PP复合材料。探讨了化学法和辐射法对PP/Mg(OH)2无卤阻燃复合材料阻燃性能和力学性能的影响。结果表明,用烷烃类偶联剂Ao-03进行表面改性的PP/Mg(OH)2具有较好的阻燃性能和力学性能,氧指数可以达到23.8%;拉伸强度变化不大,断裂伸长率达20%,是未处理PP/Mg(OH)2的9.5倍;冲击强度也最高,为未处理PP/Mg(OH)2的7倍。

【Abstract】 Different kinds of nonhalogenic flame-retardant composites were made by polypropylene(PP) as a basic material and magnesium hydroxide[Mg(OH)2] as filler treated with different surface treatment methods.The influences of chemical surface treatment and radialization surface treatment on the mechanical properties and flame-retardant properties of the composites were discussed.The results showed that the flame-retardant composite modified by Ao-03 had better flame-retardant property and good mechanical properties.The oxygen index could reach to 23.8%.While the tensile strength kept constant,its elongation at break came up to 20%.It was 9.5 times the elongation of the material in which Mg(OH)2 was untreated and it was 7 times the impact strength of the composites in which Mg(OH)2 was untreated.

【基金】 大连市青年科技基金资助项目(2003-99)
  • 【文献出处】 工程塑料应用 ,Engineering Plastics Application , 编辑部邮箱 ,2006年03期
  • 【分类号】TQ327.8
  • 【被引频次】23
  • 【下载频次】500
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