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蒙脱土对尼龙66熔融与结晶行为的影响
Influence of Montmorillonite on Melting and Crystallization Behavior of Nylon 66
【摘要】 通过 DSC方法研究了蒙脱土对尼龙 66熔融与结晶行为的影响 ,探讨了蒙脱土对尼龙 66结晶的成核作用。发现有机蒙脱土使尼龙 66的熔融峰温度 Tm 提高 5 .3℃ ,使结晶峰温度提高 1 3~ 2 4℃ ;二次熔融多产生双重熔融峰 ,蒙脱土的加入有利于生成低温峰。
【Abstract】 The influence of montmorillonite(Mont.) on melting and crystallization behavior of nylon 66 has been investigated by DSC. The results show that the melting and crystallization temperature of nylon 66 were increased by 0 5 ℃ and 13~24 ℃ respectively after adding 4 76%(by mass) of organophilic montmorillonite. The occurance of two melting peaks of PA66 and composites may be resulted from the differences of the crystal types. Addition of montmorillonite favored the production of 2 peeks in the second melting process.
【基金】 河南省杰出青年基金;河南省高等院校创新人才基金项目
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2002年10期
- 【分类号】TB332
- 【被引频次】18
- 【下载频次】242