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钇和铈掺杂对海泡石热稳定性的影响
Effects of Doping Yttrium and Cerium on Thermal Stability of Sepiolite
【摘要】 使用XRD,DTA,TG和IR以及N2吸附等手段分析了Y和Ce掺杂对海泡石结构、比表面积和热稳定性的影响。结果表明,Y和Ce的掺杂能够显著提高海泡石的比表面积,同时二者均能改善海泡石的热稳定性,其中掺Y效果更为明显。分析了产生这种现象的原因。
【Abstract】 Sepiolite modified with Ce and Y was used to investigate the effects on the thermal stability of this clay. The structure was studied by Xray diffraction. Isotherms were determined by N2 adsorption. Thermal stability was determined using XRD, DTA and TG measurements. Sepiolite doped with Y and Ce showed larger surface area than pure sepiolite. However, sepiolite doped with Y appears to be more effective than Ce doped in delaying the dehydroxylation with temperature. The intercalation of Ce and Y into sepiolite improves the thermal stability, which may increase the utility of sepiolite as catalysts.
- 【文献出处】 中国稀土学报 ,Journal of The Chinese Rare Earth Society , 编辑部邮箱 ,2002年S1期
- 【分类号】TQ170
- 【被引频次】1
- 【下载频次】103