【摘要】 合成了新的含硫希夫碱配体二苯甲酮双缩硫代氨基脲 (HL) ,在以此化合物为配体的非水溶剂中用 Cu,Zn,Fe金属作阳极 ,首次用电化学金属阳极氧化法合成了二苯甲酮双缩硫代氨基脲(HL )与 Cu( ) ,Zn( ) ,Fe( )的金属配合物。通过元素分析、红外光谱、紫外光谱、磁化率、摩尔电导等方法对配体和配合物进行了表征。更多还原

【Abstract】 The new schiff base containing sulphur 1,5-bis(benzophenone) thiocarbo-hydrazone(HL) was synthesized. Metal complexes of Cu(Ⅰ), Zn(Ⅱ), Fe(Ⅱ) were synthesized by the electrochemical oxidation of anodic metal method with Cu, Zn, Fe as anodic, in containing ligand(HL) non-aqueous solvent. The ligand and complexes were characterized by elemental analysis, IR, UV-visible spectra, magnetic susceptibility and conductance measurements, etc.更多还原