【摘要】 用滴体积法研究了温度及油酸钠 (SO)的复配对十六烷基三甲基溴化铵 (CTAB)水溶液的表面活性与胶团形成的影响。结果表明 :在 3 0 5～ 3 3 7K之间 ,CTAB的临界胶团浓度 (ccmc)随温度的升高而增大 ,形成胶团的过程是一个焓熵共同驱动的热力学自发过程 ;在 CTAB- SO复配体系中 ,正负离子表面活性剂之间存在着强烈的相互作用 ,等摩尔混合体系 (1∶ 1 )具有最高的表面活性 ,ccmc,γcmc,βm,βs和 p C2 0均具有最低值。更多还原

【Abstract】 The effect of temperature and SO mixture on the surface activity and micelle formation of the aqueous solution of CTAB has been studied by the drop volume method. Some thermodynamic parameters related to CTAB micelle have been worked out. The results indicate that at the temperature ranging from 305K to 337K,the critical micelle concentration of CTAB will increase as the temperature rises. Under certain temperature,the CTAB micelle formation process is a thermodynamically spontaneous process that was animated by the enthalpy and entropy.In the CTAB SO mixed system, the reciprocal strong action exists between the cationic and anionic surfactants, 1∶1 mixed system shows the highest surface activity. cmc, γ cmc , β m , β s and p C 20 all have minimum.更多还原