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新贮氢材料——含微量锰的微晶镁粉
A Novel Hydrogen-storage Material──Microcrystalline Mg(Mn)
【摘要】 以气雾化冷凝法制备了含有微量Mn的微晶镁粉(Mg(Mn)).XRD表明,其主物相仍然是六方晶系的微晶镁,其粒径在100~500nm之间.这种微晶镁粉(Mg(Mn))具有较高的储氢量(6.2%),在280℃具有较快的放氢速度.
【Abstract】 Microcrystalline magnesium containing a small amount of manganese(i.e.microcrystal Mg(Mn)) has been prepared by an arc vaporization condensation method. XRD indicated that the microcrystalline Mg(Mn) powder has a main phase of microcrystalline Mg remaining the hexagonal crystal structure. The TEM micrographs showed that some wadding was inlaid on the surface of the microcrystalline Mg and the particle size was about 100~500 nm. It exhibits high capacity for hydrogen storage(6.2%) and high speed for hydrogen desorption at 280 ℃. This characteristic is advantageous to the application of hydrogen storage.
【Key words】 Magnesium(Manganese); Microcrystalline; Vaporization condensation; Catalysis; Hydrogen storage;
- 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,2002年02期
- 【分类号】TB34
- 【被引频次】4
- 【下载频次】122