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[Cu(Hsal)2(py)2]n晶体结构和二维堆积网络

Crystal Structure and 2 D Stacking Network of [Cu(Hsal)2(py)2]n

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【作者】 朱龙观; 蔡国强; Susumu Kitagawa; Ho-Chol Chang;

【Author】 ZHU Long Guan*,1 CAI Guo Qiang1 Susumu Kitagawa2 Ho Chol Chang2(1Department of Chemistry, Zhejiang University, Hangzhou 310027)(2Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 606 85

【机构】 浙江大学化学系; 京都大学工学部合成·生物化学系; 京都大学工学部合成·生物化学系 杭州310027; 杭州310027; 京都606-8501日本; 京都606-8501日本;

【Abstract】 The title complex, [Cu(Hsal)2(py)2], was synthesized by layered solution technique and structurally characterized by single crystal X ray. The copper atom has a square pyramidal geometry and the coordination number is five. The molecular structure is linear one dimensional network. There is a stacking effect between pyridine ligands of neighbouring 1 D chains and the molecular structure is extended into two dimensional stacking network. Two salicylates in the complex have a position of crab pincers like, in which one salicylate is unidentate and another coordinates through the carboxylate group and phenyl group unidentately.

【基金】 国家自然科学基金资助项目(No.50073019)。
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2002年09期
  • 【分类号】O76
  • 【被引频次】7
  • 【下载频次】94
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