节点文献
[Cu(Hsal)2(py)2]n晶体结构和二维堆积网络
Crystal Structure and 2 D Stacking Network of [Cu(Hsal)2(py)2]n
【Abstract】 The title complex, [Cu(Hsal)2(py)2], was synthesized by layered solution technique and structurally characterized by single crystal X ray. The copper atom has a square pyramidal geometry and the coordination number is five. The molecular structure is linear one dimensional network. There is a stacking effect between pyridine ligands of neighbouring 1 D chains and the molecular structure is extended into two dimensional stacking network. Two salicylates in the complex have a position of crab pincers like, in which one salicylate is unidentate and another coordinates through the carboxylate group and phenyl group unidentately.
【关键词】 吡啶;
水杨酸;
晶体结构;
芳环堆积;
网络;
【Key words】 pyridine salicylic acid crystal structure stacking effect of aromatic ring network;
【Key words】 pyridine salicylic acid crystal structure stacking effect of aromatic ring network;
【基金】 国家自然科学基金资助项目(No.50073019)。
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2002年09期
- 【分类号】O76
- 【被引频次】7
- 【下载频次】94