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沉淀转化法制备的Co(OH)2的超级电容特性

Supercapacitor Characteristics of Co(OH)2 Synthesized by Deposition Transformation

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【作者】 张密林刘志祥

【Author】 ZHANG Mi Lin* LIU Zhi Xiang(Department of Chemical Engineering, Harbin Engineering University, Harbin 150001)

【机构】 哈尔滨工程大学化学工程系哈尔滨工程大学化学工程系 哈尔滨150001哈尔滨150001

【Abstract】 Cobalt hydroxide, often used as an additive in nickel electrode, is rarely studied as active material for supercapacitors. In this paper, the Co(OH)2 with the particle size less than 20nm by deposition transformation was synthesized. Its single electrode specific capacitance was measured to be 92F·g-1, and the electrode resistance was so low that the initial potential drop when discharging is unobvious even the discharge current increased to 200mA for a 1cm2 electrode. After ten thousand cycles, Co(OH)2 on the electrode changes to Co3O4 gradually, the resistance of the electrode does not increase much, while the specific capacitance increases to 133F·g-1 at 10mA。

  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2002年05期
  • 【分类号】TM533
  • 【被引频次】93
  • 【下载频次】577
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