节点文献
CVD宏观量半连续制备纳米碳管的研究
CVD Method to Synthesize Carbon Nanotubes on a Large Scale
【摘要】 研究了以乙炔为基本原料,用N2做载流气体;以纳米钻颗粒为催化剂在700~800℃常压下纳米碳管的宏观量制备.粗产品中纳米碳管的含量接近50%,而且纳米碳管缺陷很少,直而长,石墨化好.纳米碳管的形核过程是因为碳在催化剂表面分布不均匀造成的.纳米碳管的生长极限在15min左右,然后生长变得缓慢,纳米碳管的一般长度在5~30μm.
【Abstract】 Acetylene cracked under normal pressure at 700-800℃ with active nanoscale cobalt particles as catalyst and carbon nanotubes were prepared on a large scale. The final product rate was above 50wt% after 10min growth, and also defects were almost nonexistent. The lengthes of the carbon nanotubes ranged from 5 to 30μm. Non-well distributed carbon on catalyst surface accelerated the nucleating process. The growing time limitation was about 15min and then growing process became slow.
【基金】 国家自然科学基金(59872030)
- 【文献出处】 无机材料学报 ,Journal of Inorganic Materials , 编辑部邮箱 ,2002年02期
- 【分类号】TB383
- 【被引频次】12
- 【下载频次】84