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环戊二烯和甲醇催化甲基化制备甲基环戊二烯的研究——催化剂性能的考察及反应条件的确定
Study on Catalytic Methylation of Cyclopentadiene to Prepare Methylcyclopentadiene
【摘要】 对环戊二烯和甲醇催化甲基化制备甲基环戊二烯的催化剂进行反应性能考察 ,结果表明 :适宜的反应条件为反应温度 4 50℃ ,物料配比CPD :甲醇为 1∶2 .5,气相空速 12 0 0h-1 .此时 ,环戊二烯的转化率为 6 0 .6 % ,甲基环戊二烯的选择性为 79.2 % .
【Abstract】 The activity of the catalyst for methylation of cyclopentadiene was investigated. The results showed that the suitable reaction conditions are as follows: reaction temperature is 450 ℃, the ratio of cyclopentadiene(CPD) to methanol is 1∶2.5, the space velocity (ml·h \{-1\}/ml) is 1 200 h\+\{-1\}. Under the conditions the conversion for CPD is 60.6 %, the selectivity for methylcyclopentadiene (MCPD) 79.2 % and the yield of the MCPD 48.0 %.
【关键词】 环戊二烯;
甲基环戊二烯;
甲基化;
催化反应;
【Key words】 cyclopentadiene; methylcyclopentadiene; methylation; catalysis;
【Key words】 cyclopentadiene; methylcyclopentadiene; methylation; catalysis;
- 【文献出处】 沈阳化工学院学报 ,Journal of Shenyang Institute of Chemical Technolgy , 编辑部邮箱 ,2002年01期
- 【分类号】TQ231.2
- 【被引频次】2
- 【下载频次】169