【摘要】 研究了低热固相反应一步合成镧系的 8-羟基喹啉 (Oxine)配合物 Sm(Oxine) 3 ,Nd(Oxine) 3 ,Eu(Oxine) 3 ,Tb(Oxine) 3 ,经元素分析、IR及 XRD测定 ,确定了配合物的结构 ,并讨论了固相反应的机理 .更多还原

【Abstract】 Four complexes of Sm(Oxine) 3, Nd(Oxine) 3, Eu(Oxine) 3, Tb(Oxine) 3 have been synthesized by one step solid state reaction first at room temperature for 2 h, and then at 60 ℃ for about 4 h. The compositions of these complexes are confirmed by means of elemental analyses, IR and XRD. The solid state reaction mechanism is also discussed.更多还原