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TiO2/Ag光催化膜降解特种印刷工业废水的研究

PHOTOCATALYTIC DEGRADATION OF PRINTERY WASTEWATER BY TiO2/Ag MEMBRANE PHOTOCATALYST IMMOBILIZED ON ACTIVATED CARBON

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【作者】 崔鹏徐南平时钧

【Author】 CUI Peng 1,2, XU Nan-ping 1, SHI Jun 1 (1.Membrane Science and Technology Research Center, Nanjing University of Chemical Technology; Key Laboratory of Chemical Engineering and Technology of Jiangsu Province, Nanjing 210009, China 2.School of Chemical Engineering Hefei University of Technology, Hefei 230009,China)

【机构】 南京化工大学膜科学技术研究所江苏省化学工程与技术重点实验室江苏省化学工程与技术重点实验室 江苏南京210009合肥工业大学化工学院安徽合肥230009江苏南京210009江苏南京210009

【摘要】 采用溶胶 -凝胶法制备活性炭负载的 Ti O2 /Ag光催化膜 ,利用 SEM、EDS、XPS等方法对活性炭表面 Ti O2 /Ag的成膜性、主要元素及价态等进行表征。通过对特种印刷工业废水的光催化降解性能研究 ,确定了光催化剂用量、不同起始浓度、不同气量对光催化性能的影响 ;并在连续式光催化反应器中研究了该催化剂的降解能力

【Abstract】 TiO2 membrane photocatalyst immobilized on active carbon was prepared by Sol-gel technology. The element of Ag was immobilized on the TiO2 membrane by the photo-reduction method. The SEM, EDS and XPS showed that the TiO2/Ag membrane was uniform and continuous. The composite membrane photocatalyst was used for photo-degrade the printery wastewater. The data of initial COD of the wastewater was 500-900mg/L. The result of the photocatalytic degradation showed that the TiO2/Ag membrane has higher photocatalytic activity than 0.33μm TiO2 powder photocatalyst and TiO2 membrane photocatalyst. Effect of the use level of the TiO2/Ag membrane, the initial concentration of the wastewater and the gas florate on the degradation was discussed. The removal rate of COD reached 68.1% under the optimized condition after 3h irradiation. The degradation rate of the TiO2/Ag membrane photocatalyst for the printery wastewater reached 58.2% in a continuous process by a pilot plant.

  • 【文献出处】 水处理技术 ,Technology of Water Treatment , 编辑部邮箱 ,2002年06期
  • 【分类号】X703
  • 【被引频次】7
  • 【下载频次】286
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