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胶束强化超滤脱除氯苯及其膜污染的研究

STUDY ON THE REMOVAL OF CHLOROBENZENE AND MEMBRANE FOULING USING MICELLAR-ENHANCED ULTRAFILTRATION

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【作者】 许振良赛萌张志丕

【Author】 XU Zhen-liang 1, SHai men 1, ZHANG Zhi-pi 2 (1.Research Institute of Chemical Engineering, East China University of Science and Technology, Shanghai 200237,China; 2.Environmental Protection Monitor Station of Pudong New District of Shanghai, Shanghai 200000,China)

【机构】 华东理工大学化学工程研究所上海市浦东新区环境保护监测站 上海200237上海200237上海201200

【摘要】 以十六烷基氯化吡啶 (CPC)作为表面活性剂 ,利用聚醚酰亚胺 (PEI)中空纤维超滤膜 ,对含氯苯废水进行了胶束强化超滤 (MEUF)研究 ,讨论了 CPC浓度对氯苯脱除的影响 ,以及料液流速、操作压力和操作时间对膜污染的影响。在 CPC浓度 (Cf)为 3 .1 g/L~ 1 8.6 g/L的范围内 ,氯苯浓度为 0 .45 g/L时 ,CPC的截留率可大于 95 % ,而氯苯的脱除率可达 98.0 %以上 ,渗透通量可达 1 .0× 1 0 -10 m3/m2·s·Pa。采用去离子水对膜清洗 1 h后 ,膜纯水通量恢复率可达 95 %。

【Abstract】 Using hexadecylpyridinium chloride(CPC) as the surfactant, chlorobenzene as an organic pollutant to be separated, and the removal of chlorobenzene in wastewater stream was investigated by micellar-enhanced ultrafiltration(MEUF) with hollow fiber polyetherimide ultrafiltration membranes. The effect of CPC concentrations on the chlorobenzene removal and the effects of flow rates, operation pressures and operation time on membrane fouling were discussed. Within CPC concentrations of 3.1g/L~18.6g/L, the rejection rate of the surfactant (CPC) was more than 95%, the rejection of cholrobenbene was 98.0% and the permeation flux was 1.0×10-10m 3/m 2·s·Pa as the chlorobenzene concentration was 0.45g/L. After the membranes were cleaned for one hour by the deionized water, the recovery rate of pure water permeation flux reached to 95%.

【基金】 国家自然科学基金 (2 0 0 760 0 9);国家教委回国人员基金;污染控制与资源化研究国家重点实验室基金;南京大学资助项目;同济大学 (2 0 0 0 0 2 )资助项目
  • 【文献出处】 水处理技术 ,Technology of Water Treatment , 编辑部邮箱 ,2002年06期
  • 【分类号】X703
  • 【被引频次】12
  • 【下载频次】138
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