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橄榄苦甙的NMR数据解析
NMR STUDY ON OLEUROPEIN
【摘要】 对橄榄苦甙进行了1H和13C MNR检测,通过 DEPT和1H-1H COSY、HMQC、HMBC、NOESY等 2D NMR对其1H和13C NMR数据进行了全归属和较详细的解析,并指出其 NMR数据特征.
【Abstract】 Oleuropein is a well-known secoiridoid glucoside which is rich in the Oleaceae fam- ily. Its structure was confirmed during 1960~1974. It has been isolated from many plants of the genus Olea, Fraxinus, Jasminum, Ligustrum and Syringa to date. Its NMR data has been reported, but the detailed elucidation has not been given. Our recent study on the leaves of Syringa pubescens Turcz. (a Chinese folk herb) has resulted in the isolation of this constituent for the first time. In this paper, by utilizing a combination of 1D and 2D NMR techniques, its 1H and 13C NMR spectra are completely assigned and detailedly analyzed and the characteristics of its NMR data are also pointed out.
【Key words】 oleuropein; 1H and 13C NMR; 2D NMR; syringa pubescens turcz;
- 【文献出处】 波谱学杂志 ,Chinese Journal of Magnetic Resonance , 编辑部邮箱 ,2002年01期
- 【分类号】O657.2;O629
- 【被引频次】11
- 【下载频次】224