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橄榄苦甙的NMR数据解析

NMR STUDY ON OLEUROPEIN

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【作者】 赵天增尹卫平张海艳付经国吴鸣建

【Author】 ZHAO Tianzeng1, YIN Weiping2, ZHANG Haiyan1,2, FU Jingguo1 and WU Mingjian1* (1. Chemistry Institute, Henan Academy of Science, Zhengzhou 450002, China; 2. Luoyang Institute of Sc

【机构】 河南省科学院化学研究所洛阳工学院河南省科学院化学研究所 郑州 450002洛阳 471039郑州 450002洛阳工学院郑州 450002郑州 450002

【摘要】 对橄榄苦甙进行了1H和13C MNR检测,通过 DEPT和1H-1H COSY、HMQC、HMBC、NOESY等 2D NMR对其1H和13C NMR数据进行了全归属和较详细的解析,并指出其 NMR数据特征.

【Abstract】 Oleuropein is a well-known secoiridoid glucoside which is rich in the Oleaceae fam- ily. Its structure was confirmed during 1960~1974. It has been isolated from many plants of the genus Olea, Fraxinus, Jasminum, Ligustrum and Syringa to date. Its NMR data has been reported, but the detailed elucidation has not been given. Our recent study on the leaves of Syringa pubescens Turcz. (a Chinese folk herb) has resulted in the isolation of this constituent for the first time. In this paper, by utilizing a combination of 1D and 2D NMR techniques, its 1H and 13C NMR spectra are completely assigned and detailedly analyzed and the characteristics of its NMR data are also pointed out.

【关键词】 橄榄苦甙1H和13C NMR2D NMR小叶丁香
【Key words】 oleuropein1H and 13C NMR2D NMRsyringa pubescens turcz
【基金】 河南省自然科学基金资助项目(994030500)
  • 【文献出处】 波谱学杂志 ,Chinese Journal of Magnetic Resonance , 编辑部邮箱 ,2002年01期
  • 【分类号】O657.2;O629
  • 【被引频次】11
  • 【下载频次】224
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