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三七皂苷NMR研究Ⅱ──3个原人参二醇型双糖链配糖体的NMR信号全归属
NMR COMPLETE ASSIGNMENTS OF THREE PROTOPANAXADIOL BISDESMOSIDES
【摘要】 运用 2D NMR技术,如 DQF 1H-1H COSY,HMQC,HMBC,TOCSY等,对 3个原人参 二醇型双糖链配糖体人参皂甙-Rd,三七皂甙-E和六叶胆皂甙XVII的氢和碳的化学位移首次 进行了全归属.
【Abstract】 Three protopanaxadiol bisdesmosides were elucidated as ginsenoside-Rd, gypeno- side XVII, and notoginsenoside-E on the basis of MS and NMR data comparison with those in the references. The complete assignments of 1H and 13C NMR chemical shifts of these 3 compounds were obtained by means of 2D NMR spectra, such as DQF 1h-1H COSY, HMQC, HMBC and TOCSY.
【关键词】 人参皂甙-Rd;
三七皂甙-E;
七叶胆皂甙XVII;
NMR全归属;
【Key words】 ginsenoside Rd; notoginsenoside E; gypenoside XVII; NMR complete assignments;
【Key words】 ginsenoside Rd; notoginsenoside E; gypenoside XVII; NMR complete assignments;
- 【文献出处】 波谱学杂志 ,Chinese Journal of Magnetic Resonance , 编辑部邮箱 ,2002年01期
- 【分类号】O657.2;O629
- 【被引频次】22
- 【下载频次】286