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催化加氢合成二氢松油醇的研究

STUDY ON SYNTHESIS OF DIHYDROTERPINEOL BY CATALYTIC HYDROGENATION

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【作者】 黄宗凉那平李良龙曾林久

【Author】 Huang Zongliang 1, Na Ping 1, Li Lianglong 2 and Zeng Linjiu 2 (1. State Key Laboratory of C 1 Chemical Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; 2. Perfumery of Jianzhong Chemicals, Yi

【机构】 天津大学化工学院一碳化工国家重点实验室建中化工总公司香料厂建中化工总公司香料厂 天津300072天津300072宜宾644000宜宾644000

【摘要】 研究了以硼氢化钾修饰的雷尼镍催化剂催化松油醇加氢制备二氢松油醇的反应。考察了反应压力 反应温度及搅拌速率等因素对加氢过程的影响 ,确定了最佳工艺参数 ,二氢松油醇选择性达 98%以上 ,收率97.69%。

【Abstract】 The hydrogenation of terpineol to dihydroterpineol catalyzed by Raney Nickel modified by potassium borohydride was studied. The influential factors, such as reaction pressure, temperature and stirring rates were investigated, and the optimum reaction parameters were established. The selectivity of dihydroterpineol is up to 98%, and its yield is 97.69%.

  • 【文献出处】 精细石油化工 ,Speciality Petrochemicals , 编辑部邮箱 ,2002年04期
  • 【分类号】O643.3
  • 【下载频次】201
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