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原子吸收分光光度法快速测定汽油中痕量锰
DETERMINATION OF TRACE MANGANESE IN GASOLINE BY ATOMIC ABSORPTION SPECTROSCOPY
【摘要】 用原子吸收分光光度计 ,选用甲基三辛基氯化铵的甲基异丁基酮溶液作溶剂直接溶解有机试样 ,采用空气 /乙炔贫燃火焰 ,用标准曲线法定量 ,建立了一种新型高准确度测定汽油中痕量锰的定量分析方法。其回收率为 94.9%~ 1 0 8.8% ,相对标准偏差为 1 .6%
【Abstract】 A method for determination of trace manganese in gasoline by atomic absorption spectroscopy was studied. The organic samples were dissolved in methyl tricaprylammoniun chloride (MTCAC) MIBK solution, and the standard solution was prepared by dissolving MnCl 2 in Br water MTCAC MIBK solution. The samples were atomized by the poor flame of air/acetylene gas, thus it needn’t to transfer the samples into another phase through ashing and extraction, so it’s simple and quick. The recovery is 94.9%108.8%, and the RSD is 1.6%.
【关键词】 原子吸收光谱法;
痕量分析;
直接溶解试样法;
汽油;
锰;
甲基三辛基氯化铵;
甲基异丁基酮;
【Key words】 atomic absorption spectroscopy; trace analytsis; direct dissolving method; gasoline; manganese; methyl tricapryl ammonium chloride; methyl isobutyl ketone;
【Key words】 atomic absorption spectroscopy; trace analytsis; direct dissolving method; gasoline; manganese; methyl tricapryl ammonium chloride; methyl isobutyl ketone;
- 【文献出处】 精细石油化工 ,Speciality Petrochemicals , 编辑部邮箱 ,2002年02期
- 【分类号】O657.3
- 【被引频次】10
- 【下载频次】105