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N-羟乙基全氟辛酰胺甲基丙烯酸酯聚合物的合成及性能研究

Preparation and Performance Measurement of Organo-fluorine Textile Finishing Agent

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【作者】 周钰明黄静艳薛学佳

【Author】 ZHOU Yu ming,HUANG Jing yan,XUE Xue jia (Department of Chemistry and Chemical Engineering,Southeast University,Nanjing 210096,China)

【机构】 东南大学化学化工系东南大学化学化工系 江苏南京210096江苏南京210096江苏南京210096

【摘要】 以全氟辛酸为起始原料合成N 羟乙基全氟辛酰胺甲基丙烯酸酯 ,再经均聚得到溶剂型的有机氟织物整理剂。均聚物对水和二碘甲烷的接触角分别为 98 4°和 80 5° ,计算得到其表面自由能为 0 0 185J/m2 。处理后的各类织物憎水性达 10~ 11级 ,憎油性达 4~ 5级

【Abstract】 Pentadecafluorooctanoic acid was used as starting material to synthesize N (perfluorooctanoyl) aminoethyl methacrylate.Then by homopolymerization organo fluorine textile finishing agent was obtained in the form of solvent.The contact angles of water and diiodomethane to the homopolymer were 98 4° and 80 5° respectively.The surface free energy of the homopolymer was 0 0185 J/m 2.Various textiles finished by this organo fluorine textile finishing agent held water repellence 10-11 grade and oil repellence 4-5 grade.

【基金】 江苏省计经委基金资助项目 (1999-10 99-17)
  • 【分类号】TS195
  • 【被引频次】47
  • 【下载频次】226
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