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水溶液中环糊精和二取代苯包结过程热力学的可见光谱研究

Visible Spectrum Study on Thermodynamics of the Binding Process of Cyclodextrin and Di-substituted Benzene in Aqueous Solution

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【作者】 殷开梁

【Author】 YIN Kai-liang (Department of Chemical Engineering,Jiangsu Institute of Petrochemical Technology,Changzhou 213016,China)

【机构】 江苏石油化工学院化学工程系 江苏常州213016

【摘要】 报道了水溶液中β -环糊精主体与二取代苯客体包结过程的可见光谱研究结果。实验测定出不同温度下β -环糊精主体和不同二取代苯客体间包结过程的平衡常数及 2 98K时包结过程的热力学函数变量 ,结果表明 ,苯环取代基的疏水性及客体的几何构型对主客体间的包结作用存在重要影响

【Abstract】 The Vis research result of binding processes of host β-cyclodextrin and guest di-substituted benzenes in aqueous solution is reported in this article. Equilibrium constants under varied temperature and thermodynamic function variables under 298K of the binding processes were determined by the experiment. It shows that the hydrophobicity of varied aromatic substituted group and the configuration of guest have played an important role in the binding interaction between host and guest.

  • 【文献出处】 江苏石油化工学院学报 ,Journal of Jiangsu Institute of Petrochemical Technology , 编辑部邮箱 ,2002年03期
  • 【分类号】O657.31;O642
  • 【被引频次】6
  • 【下载频次】47
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